Chemical and Pharmaceutical Process Development Update Materials from the Earlier Kilomentor Articles (April-September 2007)
kilomentor | 07 March, 2009 12:26
I have seen a large increase in traffic to this blog after I reviewed the titles of some articles from December 2006 to March 2007. Therefore, I continue with this update.
Search engines have the shortcoming that they give higher rankings to recent material. This is appropriate for news, fashion and opinion but not nearly as appropriate for scientific educational materials. Thus with the passage of time it becomes harder to locate pertinent kilomentor blogs. To counteract this I am providing a review of the titles of some of the early Kilomentor articles. Regular readers can of course find all my articles in the Kilomentor archives in the kilomentor blog.
I have placed at the top the blog articles that I remember had the most visits.
Wolf & Lamb Reactions or Site Isolation Reactions
10 July, 2007
Solvent Replacement: The need to change solvent either from a reaction solvent to a crystallizing solvent or during reaction telescoping in a process
09 April, 2007
pKas of Common Organic Substances
07 June, 2007
A Practical Scheme for Working Up a Reaction Mixture based upon real Liquid-Liquid Extraction Possibilities and Logical Solubility Testing (An updated entry)
09 June, 2007
Solvent Exchanges for Special High Boiling Solvents
29 April, 2007
Polymeric Reagents and Immobilized Catalysts: When in a Process They Can Pay the Best Dividends
08 August, 2007
Urea Complexes for the Separation of Straight Chain Solvents
29 April, 20
Purification of Chemical Products by Treatment with Mixtures of Solid Adsorbants like Charcoal: Identifying Useful Absorbants by a Combinatorial Method
14 April, 20
Alcohols: Organic Chemistry Isolations with Reversible Derivatives particularly Phthalate Esters
01 April, 2007
Improved Extractive Separations with Organic/Organic Biphasic Solvent Systems: Catalyzed Total Silylation to Improve Partition Coefficients
14 May, 2007
Imminium Perchlorates & Fluoborates: Solid Crystalline Reversible Derivatives of Carbonyls
06 May, 2007
Hydrotropes as Solvents for Extraction and Separation
22 July, 2007
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Alternative for CCl4
marto | 22/08/2009, 00:53
I enjoyed reading your articles..I learned a lot from your blog..I am doing a scale up of a bromination reaction of a heterocycle using CCl4/NBS. I would like to replace this solvent..please suggest me if you got any experince with those reactions
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azeotropic mixtures
petr | 11/03/2009, 08:44
i did not find any direct contact to you, so sorry for highjacking this thread.
i just enjoyed reading your post on replacing solvents and i wonder what is your favourite reference for azeotropic mixtures. all web-based sources i found are far from being complete.